Diazidobis[2,4-diamino-6-(2-pyridyl)-1,3,5-triazine-κ2 N 1,N 6]zinc(II)
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چکیده
In the title mononuclear complex, [Zn(N(3))(2)(C(8)H(8)N(6))(2)], the Zn(II) atom, lying on a twofold rotation axis, is six-coordinated in a distorted octa-hedral environment by four N atoms from two 2,4-diamino-6-(2-pyrid-yl)-1,3,5-triazine ligands and two N atoms from two end-on-coordinated azide ions. N-H⋯N hydrogen bonds between the ligand and azide ion link the complex mol-ecules into a three-dimensional network.
منابع مشابه
Bis(azido-κN)bis[6-(pyridin-2-yl)-1,3,5-triazine-2,4-diamine-κ2 N 1,N 6]manganese(II)
In the title complex, [Mn(N(3))(2)(C(8)H(8)N(6))(2)], the complete molecule is generated by the application of twofold symmetry, and is in a distorted octa-hedral environment, coordinated by four N atoms of two bidentate 6-(pyridin-2-yl)-1,3,5-triazine-2,4-diamine ligands and two N atoms from two azide anions. The two chelated 6-(pyridin-2-yl)-1,3,5-triazine-2,4-diamine ligands form a dihedral ...
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In the title compound, [Ni(CHO(2))(2)(C(18)H(12)N(6))(H(2)O)(2)](n), the Ni(II) ion, lying on a crystallographic inversion center, has a distorted octa-hedral coordination comprising two water ligands, two O-atom donors from formate ligands and two N-atom donors from the 2,4,6-tris-(4-pyrid-yl)-1,3,5-triazine ligands. These ligands bridge the Ni(II) complex units, forming zigzag chains along th...
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The asymmetric unit of the title compound, 2C(10)H(11)N(5)O·C(6)H(10)O(4), consists of a 2,4-diamino-6-(4-meth-oxy-phen-yl)-1,3,5-triazine mol-ecule and one-half mol-ecule of adipic acid which lies about an inversion center. The triazine ring makes a dihedral angle of 12.89 (4)° with the adjacent benzene ring. In the crystal, the components are linked by N-H⋯O and O-H⋯N hydrogen bonds, thus gen...
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The complete dinuclear title complex, [Pb(2)(C(2)H(3)O(2))(2)(N(3))(2)(C(18)H(12)N(6))(2)], is generated by the application of a crystallographic centre of inversion. The Pb(II) atom is coordinated by three N atoms of the tridentate ligand, two O atoms derived from an asymmetrically coordinating acetate ligand, and two azido-N atoms derived from two asymmetrically bridging azido ligands. The me...
متن کامل2,4-Diamino-6-methyl-1,3,5-triazine ethanol solvate
The crystal structure of the title compound, C(4)H(7)N(5)·C(2)H(6)O, is determined by extensive hydrogen bonding. A sequence of dimeric associations, formed by N-H(amino)⋯N(ring), connects the triazine rings into a mol-ecular tape. Mol-ecules are linked into a supra-molecular structure by N-H⋯O and O-H⋯O hydrogen bonds. The asymmetric unit consists of two formula units.
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